QUANTIZED VIBRATIONAL DENSITIES OF STATES AND ERGODIC ENERGY-TRANSFER IN MOLECULAR-COLLISIONS

被引：45

作者：

BORJESSON, LEB ^{[1
]}

NORDHOLM, S ^{[1
]}

ANDERSSON, LL ^{[1
]}

机构：

[1] CHALMERS UNIV TECHNOL,S-41296 GOTHENBURG,SWEDEN

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 186卷 / 01期

关键词：

D O I：

10.1016/0009-2614(91)80193-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple method of generating quantized ro-vibrational densities of states based only on thermodynamic data is presented, The result is a smooth function accurate over a wide energy range. Its simple power-law form allows the ergodic collision theory limits of energy-transfer moments to be calculated analytically, revealing the nature and magnitude of the quantum effects.

引用

页码：65 / 72

页数：8

共 17 条

[1]

[Anonymous], 1972, UNIMOLECULAR REACTIO

[2] NUMBER OF MULTIPLY-RESTRICTED PARTITIONS [J].