SIMPLE SYNTHESIS AND THE DIELS-ALDER REACTION OF 3-(PARA-TOLYLTHIO)-2-(TRIMETHYLSILYLOXY)-1,3-BUTADIENE

被引：4

作者：

KOSUGI, H

HOSHINO, K

UDA, H

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 09期

关键词：

D O I：

10.1246/cl.1991.1577

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 3-(p-tolylsulfinyl)-2-butanone with trimethylsilyl trifluoromethanesulfonate in the presence of diisopropylethylamine gave 3-(p-tolylthio)-2-(trimethylsilyloxy)-1,3-butadiene (2) quantitatively. The Diels-Alder reactions of 2 and the related dienes with methyl acrylate were studied.

引用

页码：1577 / 1578

页数：2

共 5 条

[1] MODELING CHEMICAL-REACTIVITY .1. REGIOSELECTIVITY OF DIELS-ALDER CYCLOADDITIONS OF ELECTRON-RICH DIENES WITH ELECTRON-DEFICIENT DIENOPHILES [J].