SYNTHESIS AND STRUCTURE OF THE PENTAISOPROPYLCYCLOPENTADIENYL RADICAL

被引：59

作者：

SITZMANN, H ^{[1
]}

BOESE, R ^{[1
]}

机构：

[1] UNIV ESSEN GESAMTHSCH,INST ANORGAN CHEM,W-4300 ESSEN 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 08期

关键词：

D O I：

10.1002/anie.199109711

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of FeCl2 with C5iPr5Na does not yield a ferrocene derivative but instead the surprisingly stable radical C5iPr5.(.) Apparently, the bulky isopropyl substituents interfere with the formation of a sandwich structure. In the crystal, the cyclopentadienyl units are stacked along the crystallographic x axis to give a ''metal-free polydecker'' (shown on the right).

引用

页码：971 / 973

页数：3

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