2,2'-ETHYLENEBIS(ETA-5-INDENYL)TICL2

被引：5

作者：

PARKIN, S

HITCHCOCK, SR

HOPE, H

NANTZ, MH

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193007851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The TiCl2 moiety of 2,2'-ethylenebis(eta5-indenyl)titanium dichloride, [TiCl2(C20H16)], spans the mirror plane in space group Pnma, forcing disorder of the bridged bisindenyl ligand. The Ti centre has a distorted tetrahedral geometry; the (eta5-centroid)-Ti-(eta5-centroid) angle is 128.6 (2)-degrees. The indenes bend away from the TiCl2 moiety, which twists 19.1 (2)-degrees out of the cavity between the indenes.

引用

页码：169 / 171

页数：3

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