ASYMMETRIC-SYNTHESIS OF 1,4-CYCLOHEPTADIENES AND BICYCLO[3.2.1]OCTA-2,6-DIENES BY RHODIUM(II) N-(P-(TERT-BUTYL)PHENYLSULFONYL)PROLINATE CATALYZED-REACTIONS BETWEEN VINYLDIAZOMETHANES AND DIENES

被引：59

作者：

DAVIES, HML

PENG, ZQ

HOUSER, JH

机构：

[1] Department of Chemistry, Wake Forest University, Winston-Salem, NC 27109

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 48期

关键词：

D O I：

10.1016/0040-4039(94)88394-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium(ll) (S)-(N-p-(tertbutyl)phenylsulfonyl)prolinate catalyzed decomposition of vinyldiazomethanes in the presence of dienes results in a tandem cyclopropanation/Cope rearrangement, leading to a general and enantioselective approach for the construction of seven-membered carbocycles.

引用

收藏

页码：8939 / 8942

页数：4

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