PHOTOCHEMICAL REACTIONS OF AZO COMPOUNDS .15. ORTHO/PARA SUBSTITUTION RATIOS IN PHOTOINDUCED REACTIONS OF TRANS-AZOBENZENE WITH ACID CHLORIDES

被引：5

作者：

HAMON, DPG

LEWIS, GE

MAYFIELD, RJ

机构：

[1] Department of Organic Chemistry, University of Adelaide

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1968年 / 21卷 / 04期

关键词：

D O I：

10.1071/CH9681053

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Irradiation of trans-azobenzene in acetyl chloride, and subsequent hydrolysis-oxidation of the photo product, has been shown to yield a small amount of 2-chloroazo-benzene in addition to 4-chloroazobenzene (main product). Analogous reaction sequences, starting with different acid chlorides, show marked variations in ortho/para substitution ratios; and correlations indicate that the relative extents of ortho and para substitution are associated with the ionizability of the acid chlorides. © 1968 CSIRO. All rights reserved.

引用

页码：1053 / &

共 9 条

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