REACTIONS OF CUPRIC HALIDES WITH ORGANIC COMPOUNDS .3. 9-ALKYL AND 9-ARYLANTHRACENES

被引:38
作者
MOSNAIM, D
NONHEBEL, DC
RUSSELL, JA
机构
[1] Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow
关键词
D O I
10.1016/S0040-4020(01)82883-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
9-Alkyl and 9-arylanthracenes have been shown to undergo halogenation with cupric halides to give good yields of their 10-halogenated derivatives. Electron-donating groups in 9-arylanthracenes were shown to increase the rate of reaction. The results are interpreted in terms of a ligand-transfer mechanism. © 1969.
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页码:3485 / &
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