ASSESSMENT OF BRANCHING IN POLYMERS FROM SMALL-ANGLE X-RAY-SCATTERING (SAXS)

被引：38

作者：

GARG, SK ^{[1
]}

STIVALA, SS ^{[1
]}

机构：

[1] STEVENS INST TECHNOL,DEPT CHEM & CHEM ENGN,HOBOKEN,NJ 07030

来源：

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 1978年 / 16卷 / 08期

关键词：

D O I：

10.1002/pol.1978.180160808

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In the reported theoretical study, small-angle x-ray scattering from solutions was applied in assessing branching using well-characterized dextran hydrolyzates. It was found that the longitudinal and cross-sectional properties of the polysaccharides vary in a manner predictable by the molecular topology of the chains. A hydrodynamically equivalent linear model for dextran is proposed and it has been shown that this model correctly predicts values of phi prime and K, Flory's universal hydrodynamic constant and the Flory-Fox-Schaefgen parameter, respectively.

引用

页码：1419 / 1434

页数：16

共 41 条

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