AN EFFICIENT SCREEN FOR DETERMINING SOLID-STATE HYDROGEN-BONDING PATTERNS IN CARBOXYLIC-ACIDS

被引：25

作者：

VANDERHOFF, PA ^{[1
]}

LALANCETTE, RA ^{[1
]}

THOMPSON, HW ^{[1
]}

机构：

[1] RUTGERS STATE UNIV,DEPT CHEM,CARL A OLSON MEM LABS,NEWARK,NJ 07102

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 06期

关键词：

D O I：

10.1021/jo00293a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Simple crystalline keto carboxylic acids adopt hydrogen-bonding modes that are either intra- or inter-molecular, with the latter, far larger, class including carboxyl dimers and carboxyl-to-ketone catemers; it is demonstrated that symmetry-based differences between solid-state infrared and Raman spectra may be reliably used to differentiate those with dimeric H-bonding from those with noncentrosymmetric H-bonding patterns. © 1990, American Chemical Society. All rights reserved.

引用

页码：1696 / 1698

页数：3

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