POLYOXOVANADIUM ORGANOPHOSPHONATES - PROPERTIES AND STRUCTURE OF AN UNUSUAL PENTAVANADATE SPECIES WITH A V=O GROUP DIRECTED TOWARD THE INTERIOR OF THE MOLECULAR CAVITY

被引：29

作者：

CHEN, Q ^{[1
]}

ZUBIETA, J ^{[1
]}

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1002/anie.199302611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unsymmetrical bowllike(~)\V3O5(PhPO3)4\ framework (V2 - V4, P1 - P4), on whose surface a VO unit (V1) is ''condensed'', and which is capped by octahedrally coordinated V atom (V5), is formed by the anion of 1 . CH3OH. A terminal oxo group (O23) is encapsulated in this cavity (phenyl substituents at P1. P3. P4 are omitted from the structure shown right). (Bu4N)[V5O7(OCH3)2(PhPO3)5] 1

引用

页码：261 / 263

页数：3

共 29 条

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