Study of fire-retardant polymers using temperature jump Fourier transform infrared spectroscopy

被引:10
作者
Nagasawa, Y [1 ]
Yamamoto, M [1 ]
Ozawa, K [1 ]
机构
[1] TORAY RES CTR LTD, NAGOYA LAB, MINATO KU, NAGOYA, AICHI 455, JAPAN
关键词
pyrolysis; FT-IR; time-resolve; fire-retardant polymer; evolved gas;
D O I
10.1016/0040-6031(95)02480-8
中图分类号
O414.1 [热力学];
学科分类号
摘要
In this study we applied temperature jump/Fourier transform infrared spectroscopy, once called fast thermolysis/FT-IR spectroscopy, to quantify the thermal decomposition gases from two kinds of fire-retardant polymers. In the case of nylon-6, the addition of melamine-cyanurate accelerated the reduction of molecular weight, which caused the function of molten polymer drip away from the ignited flame. In the case of a fire-retardant PET, the evolution of a large amount of carbon dioxide (incombustible gas) dominated in the extinguishing stage.
引用
收藏
页码:223 / 230
页数:8
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