STEREOCHEMISTRY OF ASYMMETRIC SILICON .14. SN2]-SI MECHANISM AND RACEMIZATION OF AN OPTICALLY ACTIVE FLUOROSILANE WITHOUT DISPLACEMENT OF FLUORIDE ION

被引：32

作者：

SOMMER, LH

BAUMAN, DL

机构：

[1] Department of Chemistry, University of California, Davis

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 25期

关键词：

D O I：

10.1021/ja01053a026

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A kinetic study of the alcohol-induced racemization of optically active α-naphthylphenylmethylfluoro-silane, R3Si*F, has been carried out. The data have been rationalized in terms of mechanism Sn2*-Si which involves the equilibrium formation of an expanded-octet addition complex between the reagent and the fluorosilane. © 1969, American Chemical Society. All rights reserved.

引用

收藏

页码：7045 / &

相关论文

共 32 条

[1] STRUCTURAL STUDIES OF PENTACOORDINATE SILICON .2. PHENYL (2,2',2'' -NITRILOTRIPHENOXY) SILANE [J].

BOER, FP ;

TURLEY, JW ;

FLYNN, JJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (19) :5102-&

[2]

COREY JY, 1963, J AM CHEM SOC, V85, P4043

[3] ORGANOSILICON COMPOUNDS .4. THE PREPARATION OF ORGANOFLUOROSILANES [J].

EABORN, C .

JOURNAL OF THE CHEMICAL SOCIETY, 1952, (JUL) :2846-2849

[4]

EABORN C, 1960, ORGANOSILICON COMPOU, P110

[5]

ELIEL EL, 1962, STEREOCHEMISTRY CARB, P34

[6] PENTACOORDINATE SILICON DERIVATIVES .2. SALTS OF BIS(OMICRON-ARYLENEDIOXY)ORGANOSILICONIC ACIDS [J].

FRYE, CL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (15) :3170-&

[7]

FRYE CL, 1961, J AM CHEM SOC, V83, P996

[8] PENTACOORDINATE SILICON DERIVATIVES .3. 2,2',2''-NITRILOTRIPHENOL A NEW CHELATING AGENT [J].

FRYE, CL ;

VINCENT, GA ;

HAUSCHIL.GL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (12) :2727-&

[9] STRONG HYDROGEN BONDS .2. HYDROGEN DIFLUORIDE ION [J].

HARRELL, SA ;

MCDANIEL, DH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (20) :4497-&

[10] AN ELECTRON IMPACT STUDY OF IONIZATION AND DISSOCIATION OF TRIMETHYLSILANES [J].

HESS, GG ;

LAMPE, FW ;

SOMMER, LH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (23) :5327-&

← 1 2 3 4 →