SYNTHESIS AND PROPERTIES OF (C5H5CO)B9H9C-N(CH3)3 AND RELATED DERIVATIVES

被引：17

作者：

SCHULTZ, RV ^{[1
]}

HUFFMAN, JC ^{[1
]}

TODD, LJ ^{[1
]}

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 10期

关键词：

D O I：

10.1021/ic50200a051

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of B9H11C•N(CH3)3 with NaH and subsequent treatment with NaC5H5 and CoCl2 formed (C5H5Co)B9H9GN(CH3)3. This closo 11-atom molecule is fluxional at +70 °C and static at -40 °C on the 11B NMR time scale. Thermal degradation of the cobalt complex formed B9H9C•NCH3)3. Reaction of B9H11C•N(CH3)3 with sodium polyselenide formed nido-SeB9H, C•N(CH3)3 in moderate yield. © 1979, American Chemical Society. All rights reserved.

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页码：2883 / 2886

页数：4

相关论文

共 24 条

[1]

DOLANSKY J, 1976, CHEM IND LONDON, P856

[2] 1ST HYPHO-CARBABORANE ME3N-CB5H11 [J].

DUBEN, J ;

HERMANEK, S ;

STIBR, B .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (07) :287-287

[3] FORMATION OF CB5H9 AND ITS 1-METHYL DERIVATIVE FROM 1,7-C2B6H8 [J].

DUNKS, GB ;

HAWTHORN.MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (26) :7355-&

[4] FORMATION OF 2-CARBA-NIDO-HEXABORANE(9) AND SEVERAL OF ITS ALKYL DERIVATIVES [J].

DUNKS, GB ;

HAWTHORN.MF .

INORGANIC CHEMISTRY, 1969, 8 (12) :2667-&

[5] THERMAL REARRANGEMENTS OF NONICOSAHEDRAL COBALTACARBORANES [J].

DUSTIN, DF ;

EVANS, WJ ;

JONES, CJ ;

WIERSEMA, RJ ;

GONG, H ;

CHAN, S ;

HAWTHORN.MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (10) :3085-3090

[6] SYNTHESIS OF 9-VERTEX MONOCARBON METALLOCARBORANES BY POLYHEDRAL CONTRACTION [J].

DUSTIN, DF ;

HAWTHORN.MF .

INORGANIC CHEMISTRY, 1973, 12 (06) :1380-1383

[7] SYNTHESIS OF METALLOCARBORANES BY POLYHEDRAL EXPANSION [J].

EVANS, WJ ;

DUNKS, GB ;

HAWTHORN.MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (14) :4565-4574

[8]

EVANS WJ, 1971, J AM CHEM SOC, V93, P3063

[9] INSERTION OF SELENIUM, TELLURIUM, OR ARSENIC ATOMS INTO BORANE CAGE COMPOUNDS USING ELEMENT OXIDE REAGENTS [J].

FRIESEN, GD ;

TODD, LJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (08) :349-350

[10]

FRIESEN GD, 1978, CHEM IND-LONDON, P631