ELECTROCHEMICAL STUDIES OF POLY(MERCAPTOHYDROQUINONE) AND POLY(MERCAPTO-PARA-BENZOQUINONE) FILMS PREPARED BY ELECTROCHEMICAL POLYMERIZATION .6. ELECTROREDUCTION OF L-CYSTINE ON THIOLATES FIXED IN THE POLYMER FILM

被引:7
作者
ARAI, G
SUGAYA, T
SAKAMOTO, M
YASUMORI, I
机构
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D O I
10.1246/bcsj.65.594
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Electrocatalytic reduction of L-cystine (CySSCy) was examined on glassy carbon electrodes coated with the title conductive polymer in which Pt, Pd, Cu, Ag, and Hg thiolates were fixed. Pt and/or Pd thiolate fixed in the polymer behaved as excellent electrocatalytic active sites for reductive cleavage of the sulfur sulfur bond in CySSCy.
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页码:594 / 596
页数:3
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