SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DOUBLE BARIUM TITANIUM ISOPROPOXIDE [BA4TI4(MU-4-O)4(MU-3-OR)2(MU-OR)8(OR)6(ROH)4][BA4TI4(MU-4-O)4(MU-3-OR)2(MU-OR)9(OR)5(ROH)3]

被引：45

作者：

YANOVSKY, AI

YANOVSKAYA, MI

LIMAR, VK

KESSLER, VG

TUROVA, NY

STRUCHKOV, YT

机构：

[1] LY KARPOV PHYS CHEM RES INST, MOSCOW 103064, USSR

[2] MV LOMONOSOV STATE UNIV, DEPT CHEM, MOSCOW 117234, USSR

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 22期

关键词：

D O I：

10.1039/c39910001605

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An X-ray structural study of the crystals isolated from the solutions obtained by the reaction of Ba metal with Ti(OPr(i))4 in isopropyl alcohol has been carried out; the crystals of the compound, which is a precursor for the synthesis of BaTiO3, contain molecules of two different kinds [Ba4Ti4O4(OR)16(ROH)4] and [Ba4Ti4O4(OR)16(ROH)3], where R = Pr(i).

引用

页码：1605 / 1606

页数：2

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