ON THE INTERGROWTH OF THE SILVER-OXIDES AG2O3 AND AG3O4

被引：3

作者：

FISCHER, P ^{[1
]}

JANSEN, M ^{[1
]}

机构：

[1] UNIV BONN,INST ANORGAN CHEM,GERHARD DOMAGK STR 1,W-5300 BONN 1,GERMANY

来源：

ACTA CHEMICA SCANDINAVICA | 1991年 / 45卷 / 08期

关键词：

D O I：

10.3891/acta.chem.scand.45-0816

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A new silver oxide has been detected by cyclic voltammetry and X-ray powder techniques. It is formed during the anodic oxidation of aqueous silver (I) electrolytes [c(Ag+) = 0.3 mol dm-3, c(F-) = 0.3 mol dm-3, c(ClO4-) = 1.4 mol dm-3, i = 50 mA cm-2]. The new phase is shown to be an intergrowth of Ag3O4 and Ag2O3 with the hypothetical composition range Ag(x)O(y); 3/4 > x/y > 2/3.

引用

页码：816 / 819

页数：4

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