SELECTIVE REDUCTION OF ALKYNES TO Z-ALKENES USING HYDROSILANE FUNCTIONS IMMOBILIZED ON SILICA-GEL

被引：18

作者：

KINI, AD ^{[1
]}

NADKARNI, DV ^{[1
]}

FRY, JL ^{[1
]}

机构：

[1] UNIV TOLEDO,DEPT CHEM,BOWMAN ODDY LABS,TOLEDO,OH 43606

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(00)76744-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A solid reagent consisting of hydrosilane functions immobilized on the surface of silica gel was used in conjunction with acetic acid and tetrakis(triphenylphosphine)palladium(0) catalyst to effect the reduction of alkynes to Z-olefins. Simple filtration provides a convenient means far the reaction workup and isolation of products.

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页码：1507 / 1510

页数：4

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