OXIDATIVE GENERATION OF N-ACYLIMINIUM IONS FROM N-1-(TRIBUTYLSTANNYL)ALKYL CARBOXAMIDES AND CARBAMATES AND THEIR REACTIONS WITH CARBON NUCLEOPHILES

被引：27

作者：

NARASAKA, K

KOHNO, Y

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 11期

关键词：

D O I：

10.1246/bcsj.66.3456

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation of N-1-(tributylstannyl)alkyl carboxamides and carbamates with ammonium hexanitratocerate(IV) or ferrocenium hexafluorophosphate generates their N-acyliminium ions by the elimination of tributylstannyl radical under mild reaction conditions. The iminium ions thus formed react with various carbon nucleophiles to give the corresponding addition products.

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页码：3456 / 3463

页数：8

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