NEW RING-OPENING REACTION OF THIIRANES WITH CARBOXYLIC-ACID DERIVATIVES CATALYZED BY QUATERNARY ONIUM SALTS

被引：32

作者：

KAMEYAMA, A ^{[1
]}

KIYOTA, M ^{[1
]}

NISHIKUBO, T ^{[1
]}

机构：

[1] KANAGAWA UNIV,FAC ENGN,DEPT APPL CHEM,KANAGAWA KU,YOKOHAMA 221,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 26期

关键词：

RING-OPENING REACTION; THIIRANES; CARBOXYLIC ACID DERIVATIVES; QUATERNARY ONIUM SALTS;

D O I：

10.1016/S0040-4039(00)60731-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New ring-opening reaction of thiiranes with carboxylic acid derivatives having good leaving groups was investigated. The reaction of thiiranes with acyl chlorides or S-aryl thioesters using quaternary onium salts as neutral catalysts proceeded very smoothly and regioselectively to afford the corresponding S-thioesters as addition products.

引用

页码：4571 / 4574

页数：4

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