STUDIES IN MASS SPECTROMETRY . DOUBLE HYDROGEN MIGRATION IN ADDUCTS OF P-BENZOQUINONE WITH BI-1-CYCLOALKEN-1-YLS UNDER ELECTRON IMPACT

被引：24

作者：

DEUTSCH, J

MANDELBA.A

机构：

[1] Department of Chemistry, Israel Institute of Technology, Haifa

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 17期

关键词：

D O I：

10.1021/ja01045a039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The retro-Diels-Alder fragmentation of the adducts (I) of p-benzoquinone with bi-1-cyclohexen-1-yl and with related dienes under electron impact is accompanied by double hydrogen migration. Examination of the mass spectra of deuterium-labeled adducts revealed that the two migrating atoms are attached at positions 8 and 9. A possible mechanism is suggested. © 1969, American Chemical Society. All rights reserved.

引用

页码：4809 / &

共 27 条

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