MASS-SPECTROMETRY OF UNDERIVATIZED NATURALLY-OCCURRING GLYCOSIDES

被引：55

作者：

WOLFENDER, JL ^{[1
]}

MAILLARD, M ^{[1
]}

MARSTON, A ^{[1
]}

HOSTETTMANN, K ^{[1
]}

机构：

[1] UNIV LAUSANNE, SCH PHARM, INST PHARMACOGNOSY & PHYTOCHEM, BEP, CH-1015 LAUSANNE, SWITZERLAND

来源：

PHYTOCHEMICAL ANALYSIS | 1992年 / 3卷 / 05期

关键词：

MASS SPECTROMETRY; SOFT IONIZATION; GLYCOSIDES;

D O I：

10.1002/pca.2800030502

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Mass spectrometry is essential for the structure determination of naturally occurring glycosides. Molecular weight and sugar sequence information can be obtained. Development of "soft" ionization techniques has allowed a direct mass spectrometric investigation of underivatized glycosides. Numerous different and complementary methods of ionization have been used for their study. For a given compound, the choice of a particular technique is crucial in order to obtain the structural information needed. A brief survey of these ionization techniques is given, together with examples of their use in major classes of plant glycosides.

引用

页码：193 / 214

页数：22

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