FUNCTIONAL MONOMERS AND POLYMERS .86. PHOTOCHEMICAL-REACTIONS ON SYNTHETIC-POLYMERS WITH PENDANT THYMINE BASES - EFFECT OF SOLVENTS

被引：33

作者：

KITA, Y ^{[1
]}

UNO, T ^{[1
]}

INAKI, Y ^{[1
]}

TAKEMOTO, K ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT PETROCHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1981年 / 19卷 / 02期

关键词：

OLIGOMERS - Microstructure - POLYMERIZATION - Photochemical Reactions - SOLVENTS - Chemistry - SPECTROSCOPY; ULTRAVIOLET; -; VISCOSITY;

D O I：

10.1002/pol.1981.170190221

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In the reported experiments, photodimerization of thymine bases present on the side chain of acryloyl and methacryloyl-type polymers was studied in dimethyl sulfoxide, dimethylformamide, and dimethyl sulfoxide-ethylene glycol mixture. Quantum efficiencies for photodimerization and quenching with isoprene were influenced by the solvents. The self-association of thymine bases estimated from their ultraviolet (UV) spectra and intrinsic viscosity were related to the effect of solvent on the photodimerization.

引用

页码：477 / 485

页数：9

共 5 条

[1] FUNCTIONAL MONOMERS AND POLYMERS .47. COMPLEX-FORMATION OF STEREOREGULAR METHACRYLOYL-TYPE POLYMERS CONTAINING NUCLEIC-ACID BASES [J].

AKASHI, M ;

OKIMOTO, T ;

INAKI, Y ;

TAKEMOTO, K .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1979, 17 (03) :905-916

[2]

FISHER GJ, 1976, PHOTOCHEM PHOTOBIOL, P225

[3] FUNCTIONAL MONOMERS AND POLYMERS .63. A STUDY ON THE POLYMER-POLYMER INTERACTION BETWEEN NUCLEIC-ACID BASE-SUBSTITUTED POLY-L-LYSINES [J].

ISHIKAWA, T ;

INAKI, Y ;

TAKEMOTO, K .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (03) :949-958

[4] FUNCTIONAL MONOMERS AND POLYMERS .61. PHOTOCHEMICAL-REACTIONS ON THE SYNTHETIC-POLYMERS CONTAINING THYMINE BASES [J].

KITA, Y ;

INAKI, Y ;

TAKEMOTO, K .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (02) :427-439

[5]

Takemoto K, 1976, J POLYM SCI POLYM S, V55, P105

← 1 →