FIRST X-RAY STRUCTURAL DETERMINATION OF FULLERENE [2+2] CYCLOADDUCT

被引：27

作者：

ISHIDA, T

SHINOZUKA, K

NOGAMI, T

SASAKI, S

IYODA, M

机构：

[1] UNIV ELECTROCOMMUN, DEPT APPL PHYS & CHEM, CHOFU, TOKYO 182, JAPAN

[2] TOKYO METROPOLITAN UNIV, FAC SCI, DEPT CHEM, HACHIOJI, TOKYO 19203, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 04期

关键词：

D O I：

10.1246/cl.1995.317

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

X-Ray crystallographic analysis of a 1:1 adduct of C-60 and 4,5-dimethoxybenzyne exhibited a benzocyclobutene structure given by [2+2] cycloaddition reaction at a 6,6-ring junction. A fullerene C(sp(3))-C(sp(3)) bond length is 1.645(8) Angstrom. Relatively shore intermolecular C...C, C...O, and C...S distances were found, where sulfur atoms belong to CS2 molecules enclosed.

引用

页码：317 / 318

页数：2

共 19 条

[1] ABSOLUTE-CONFIGURATION OF BENZOCYCLOBUTENE HOMOISOFLAVANONES FROM MUSCARI SPECIES
ADINOLFI, M
BARONE, G
GIORDANO, F
LANZETTA, R
PARRILLI, M
[J]. TETRAHEDRON, 1990, 46 (18) : 6565 - 6574
[2] THE DIELS-ALDER ADDUCT OF C-60 AND 4,5-DIMETHOXY-O-QUINODIMETHANE SYNTHESIS, CRYSTAL-STRUCTURE, AND DONOR-ACCEPTOR BEHAVIOR
BELIK, P
GUGEL, A
KRAUS, A
SPICKERMANN, J
ENKELMANN, V
FRANK, G
MULLEN, K
[J]. ADVANCED MATERIALS, 1993, 5 (11) : 854 - 856
[3] STRUCTURES AND DEFORMATION ELECTRON-DENSITIES OF 1,2-DIHYDROCYCLOBUTABENZENE AND 1,2,4,5-TETRAHYDRODICYCLOBUTA[A,D]BENZENE
BOESE, R
BLASER, D
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (02): : 304 - 305
[4] REACTION OF [70]FULLERENE WITH BENZYNE
DARWISH, AD
ABDULSADA, AK
LANGLEY, GJ
KROTO, HW
TAYLOR, R
WALTON, DRM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (18) : 2133 - 2134
[5] SYNTHESIS OF A FULLERENE DERIVATIVE OF BENZO[18]CROWN-6 BY DIELS-ALDER REACTION - COMPLEXATION ABILITY, AMPHIPHILIC PROPERTIES, AND X-RAY CRYSTAL-STRUCTURE OF A DIMETHOXY-1,9-(METHANO[1,2]BENZENOMETHANO)FULLERENE[60]BENZENE CLATHRATE
DIEDERICH, F
JONAS, U
GRAMLICH, V
HERRMANN, A
RINGSDORF, H
THILGEN, C
[J]. HELVETICA CHIMICA ACTA, 1993, 76 (07) : 2445 - 2453
[6] ABINITIO STUDY OF SIGMA-EFFECTS AND PI-EFFECTS IN BENZENES FUSED TO 4-MEMBERED RINGS - REHYBRIDIZATION, DELOCALIZATION, AND ANTIAROMATICITY
FAUST, R
GLENDENING, ED
STREITWIESER, A
VOLLHARDT, KPC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (21) : 8263 - 8268
[7] Hirsch A, 1994, CHEM FULLERENES, P80
[8] HOFFMANN RW, 1967, DEHYDROBENZENE CYCLO, P200
[9] REACTION OF FULLERENES AND BENZYNE
HOKE, SH
MOLSTAD, J
DILETTATO, D
JAY, MJ
CARLSON, D
KAHR, B
COOKS, RG
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (19) : 5069 - 5071
[10] IRMGARTINGER H, 1994, CHEM BER, V127, P581

← 1 2 →