SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [H5O2+CENTER-DOT-21-CROWN-7][WOCL5-], A COMPLEX IN WHICH THE 21-CROWN-7 MOLECULE ADOPTS A RIGID, BOWL-LIKE CONFORMATION

被引：25

作者：

JUNK, PC ^{[1
]}

ATWOOD, JL ^{[1
]}

机构：

[1] UNIV MISSOURI,DEPT CHEM,COLUMBIA,MO 65211

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 15期

关键词：

D O I：

10.1039/c39950001551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of W(CO)(6) with 21-crown-7 in the presence of H2O and HCl(g) in toluene has yielded [H5O2+. 21-crown-7][WOCl5-], a complex exhibiting a bowl-like conformation for the 21-crown-7 molecule which is bound to an H5O2+ ion in the unusual, high energy cis conformation.

引用

页码：1551 / 1552

页数：2

共 39 条

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