ABSOLUTE STEREOCHEMISTRY AND NOVEL RING-OPENING OXIDATION OF METHYL (R)-2-HYDROXYSTERCULATE

被引：5

作者：

NAKATANI, M

HASE, T

机构：

[1] Department of Chemistry, Faculty of Science, Kagoshima University, 1-21-35 Korimoto, Kagoshima

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 10期

关键词：

D O I：

10.1246/bcsj.64.3084

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cyclopropene-ring-containing fatty acid ester, methyl (R)-2-hydroxysterculate, was isolated from Hibiscus rosa-sinensis along with methyl sterculate and malvalate. The stereochemistry of the asymmetric carbon at C-2 was determined as R by applying a dibenzoate chirality method, and a mild air oxidation afforded two conjugated enone isomers accompanying a ring opening.

引用

页码：3084 / 3088

页数：5

共 20 条

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