UNEXPECTED CATALYTIC AND STEREOSELECTIVE HYDROARYLATION OF NORBORNENE DURING THE ATTEMPTED RHODIUM-CATALYZED HYDROAMINATION OF NORBORNENE WITH ANILINE OR DIPHENYLAMINE

被引：43

作者：

BRUNET, JJ ^{[1
]}

NEIBECKER, D ^{[1
]}

PHILIPPOT, K ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 17期

关键词：

D O I：

10.1039/c39920001215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of aniline (or diphenylamine) with norbornene in the presence of a catalytic system generated from [{Rh(PEt3)2Cl}2] and PhNHLi (or Ph2NLi) results in hydroarylation to yield 2-(2-aminophenyl)norbornane [or 2-(2-phenylaminophenyl)norbornane].

引用

页码：1215 / 1216

页数：2

共 15 条

[1] PALLADIUM-CATALYZED PREPARATION OF EXO-ARYL DERIVATIVES OF THE NORBORNANE SKELETON
ARCADI, A
MARINELLI, F
BERNOCCHI, E
CACCHI, S
ORTAR, G
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 368 (02) : 249 - 256
[2] FUNCTIONALIZATION OF ALKENES - CATALYTIC AMINATION OF MONOOLEFINS
BRUNET, JJ
NEIBECKER, D
NIEDERCORN, F
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1989, 49 (03): : 235 - 259
[3] RATIONAL DESIGN IN HOMOGENEOUS CATALYSIS - IR(I)-CATALYZED ADDITION OF ANILINE TO NORBORNYLENE VIA N-H ACTIVATION
CASALNUOVO, AL
CALABRESE, JC
MILSTEIN, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (20) : 6738 - 6744
[4] AMIDES OF RHODIUM(I) AND RUTHENIUM(II), [RH(NR2)(PPH3)2] AND [RUH(NR2)(PPH3)2] (R=ME3SI) - NOVEL LOW COORDINATION NUMBER D8 AND D6 METAL-COMPLEXES
CETINKAYA, B
LAPPERT, MF
TORRONI, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (19) : 843 - 844
[5] COULSON DR, 1971, TETRAHEDRON LETT, P429
[6] COULSON DR, 1973, Patent No. 3758586
[7] AMIDES OF THE PLATINUM GROUP-METALS
FRYZUK, MD
MONTGOMERY, CD
[J]. COORDINATION CHEMISTRY REVIEWS, 1989, 95 (01) : 1 - 40
[8] AMINATION OF ALKENES
GASC, MB
LATTES, A
PERIE, JJ
[J]. TETRAHEDRON, 1983, 39 (05) : 703 - 731
[9] STRUCTURE, SYNTHESIS, AND CHEMISTRY OF (PME3)4RU(ETA-2-BENZYNE) - REACTIONS WITH ARENES, ALKENES, AND HETEROATOM-CONTAINING ORGANIC-COMPOUNDS - SYNTHESIS AND STRUCTURE OF A MONOMERIC HYDROXIDE COMPLEX
HARTWIG, JF
BERGMAN, RG
ANDERSEN, RA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (09) : 3404 - 3418
[10] SYNTHESIS AND CHEMISTRY OF RUTHENIUM HYDRIDO ARYLOXIDES AND ARYLAMIDES - AN INVESTIGATION OF STRUCTURE, N-H AND O-H ELIMINATION PROCESSES, PROTON-CATALYZED EXCHANGE-REACTIONS, AND RELATIVE RU-X BOND STRENGTHS
HARTWIG, JF
ANDERSEN, RA
BERGMAN, RG
[J]. ORGANOMETALLICS, 1991, 10 (06) : 1875 - 1887

← 1 2 →