PREPARATION, CRYSTAL AND ELECTRONIC-STRUCTURES, AND ELECTRICAL-RESISTIVITY OF (BEDT-TTF)3CL2.5(H5O2)

被引：11

作者：

MORI, H ^{[1
]}

HIRABAYASHI, I ^{[1
]}

TANAKA, S ^{[1
]}

MARUYAMA, Y ^{[1
]}

机构：

[1] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 08期

关键词：

D O I：

10.1246/bcsj.66.2156

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal and electronic structures and electrical resistivity of new chlorine complex, (BEDT-TTF)3Cl2.5(H5O2), were investigated. The two-dimensional donor sheet and the anion layer stack alternately along the b-axis. The packing pattern of donors is similar to that of (BEDT-TTF)3(ClO4)2 and the sharp metal-insulator transition was observed at 170 K. It is interesting that not only donor and anion but also the third component cation, H+, determines the 3/4-filled band structure.

引用

页码：2156 / 2159

页数：4

共 16 条

[1] BRAVIC G, 1991, SYNTHETIC MET, V41, P2035
[2] KOBAYASHI H, 1984, CHEM LETT, P179, DOI 10.1246/cl.1984.179
[3] CRYSTAL-STRUCTURES AND ELECTRICAL-PROPERTIES OF BEDT-TTF COMPOUNDS
KOBAYASHI, H
KATO, R
MORI, T
KOBAYASHI, A
SASAKI, Y
SAITO, G
ENOKI, T
INOKUCHI, H
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1984, 107 (1-2): : 33 - 43
[4] SUPERCONDUCTIVITY IN (BEDT-TTF)4PT(CN)4H2O
MORI, H
HIRABAYASHI, I
TANAKA, S
MORI, T
MARUYAMA, Y
INOKUCHI, H
[J]. SOLID STATE COMMUNICATIONS, 1991, 80 (06) : 411 - 415
[5] A NEW AMBIENT-PRESSURE ORGANIC SUPERCONDUCTOR, KAPPA-(BEDT-TTF)2AG(CN)2H2O (TC=5.0 K)
MORI, H
HIRABAYASHI, I
TANAKA, S
MORI, T
INOKUCHI, H
[J]. SOLID STATE COMMUNICATIONS, 1990, 76 (01) : 35 - 37
[6] MORI H, 1991, SYNTHETIC MET, V41, P2013
[7] THE INTERMOLECULAR INTERACTION OF TETRATHIAFULVALENE AND BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE IN ORGANIC METALS - CALCULATION OF ORBITAL OVERLAPS AND MODELS OF ENERGY-BAND STRUCTURES
MORI, T
KOBAYASHI, A
SASAKI, Y
KOBAYASHI, H
SAITO, G
INOKUCHI, H
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (03) : 627 - 633
[8] STRUCTURAL AND ELECTRICAL-PROPERTIES OF (BEDT-TTF)3CL2(H2O)2
MORI, T
INOKUCHI, H
[J]. CHEMISTRY LETTERS, 1987, (08) : 1657 - 1660
[9] SUPERCONDUCTIVITY IN (BEDT-TTF)3CL22H2O
MORI, T
INOKUCHI, H
[J]. SOLID STATE COMMUNICATIONS, 1987, 64 (03) : 335 - 337
[10] MORI T, 1992, SOLID STATE COMMUN, V82, P35

← 1 2 →