REACTION OF DICYCLOPENTADIENYLDIPHENYLTITANIUM WITH PHENYLLITHIUM

被引：18

作者：

LATYAEVA, VN

VYSHINSK.LI

SHUR, VB

FYODOROV, LA

VOLPIN, ME

机构：

[1] Department of Chemistry, Gorky State University, Gorky

[2] Institute of Organo-Element Compounds, Academy of Sciences, Moscow

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 16卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81640-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of dicyclopentadienyldiphenyltitanium with phenyllithium in ether solution takes place with reduction of titanium(IV) to titanium(III) and then to titanium(II). The reaction products in the presence of excess phenyllithium are diphenyltitanium, cyclopentadienyllithium, benzene, metallic lithium and small amounts of diphenyl and triphenylene. Titanium compounds were found to catalyse the decomposition of phenyllithium to benzene and lithium. © 1969.

引用

页码：103 / &

共 6 条

[1] LATYAEVA VN, 1964, J ORGANOMET CHEM, V2, P388
[2] CYCLOPENTADIENYL-THALLIUM
MEISTER, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1957, 69 (16) : 533 - 534
[3] RAZUVAEV GA, 1964, DOKL AKAD NAUK SSSR+, V159, P383
[4] RAZUVAEV GA, 1966, ZH OBSHCH KHIM, V36, P1491
[5] REACTION OF BIS-(CYCLOPENTADIENYL)-TITANIUM DICHLORIDE WITH ARYLLITHIUM COMPOUNDS
SUMMERS, L
ULOTH, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (08) : 2278 - 2279
[6] SUMMERS L, 1957, PB34 REPT, P15

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