CRYSTAL-STRUCTURE OF 2-FLUOROACETAMIDATO-BRIDGED MIXED-VALENT OCTANUCLEAR PLATINUM BLUE WITH AVERAGE PLATINUM OXIDATION-STATE OF 2.08, [PT8(NH3)16(CH2FCONH)8](NO3)8.66.4H2O

被引：18

作者：

SAKAI, K

MATSUMOTO, K

NISHIO, K

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 07期

关键词：

D O I：

10.1246/cl.1991.1081

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Red-purple plate crystals of [Pt8(NH3)16 (CH2FCONH)8] (NO3)8.66.4H2O have been prepared and the crystal structure is reported. Magnetic susceptibility measurement revealed that the compound is a mixture of [PT(2.0+)8(NH3)16(CH2FCONH)8]8+(PT(2.0+)8) and [Pt(2.125+)8(NH3)16-(CH2FCONH)8]9+(Pt(2.125+)8), and the mixed ratio is Pt(2.125)8/Pt(2.0+)8 = 1.97.

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页码：1081 / 1084

页数：4

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