EXCESS MOLAR ENTHALPIES OF METHYL TERT-BUTYL ETHER + N-HEXANE + (N-DECANE OR N-DODECANE) TERNARY MIXTURES AT 29815-K

被引：63

作者：

WANG, L ^{[1
]}

BENSON, GC ^{[1
]}

LU, BCY ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM ENGN,OTTAWA K1N 9B4,ONTARIO,CANADA

来源：

THERMOCHIMICA ACTA | 1993年 / 213卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0040-6031(93)80007-W

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Excess molar enthalpies, measured at 298.15 K in a flow microcalorimeter, are reported for the ternary mixtures x1C5H12O + x2C6H14 + x3CvH2v+2, with v = 10 and 12. Smooth representations of the results are described and used to construct contours of constant enthalpy on a Roozeboom diagram. An analysis of the results in terms of the Flory theory of mixtures is also presented.

引用

页码：83 / 93

页数：11

共 15 条

[1] THERMODYNAMIC PROPERTIES OF MIXTURES OF SMALL NONPOLAR MOLECULES [J].

ABE, A ;

FLORY, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) :1838-&

[2] PREDICTION OF THERMODYNAMIC PROPERTIES OF TERNARY LIQUID SOLUTIONS INCLUDING METAL-ALLOYS [J].

BROSTOW, W ;

SOCHANSKI, JS .

JOURNAL OF MATERIALS SCIENCE, 1975, 10 (12) :2134-2145

[3] STATISTICAL THERMODYNAMICS OF LIQUID MIXTURES [J].

FLORY, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) :1833-+

[4] EXCESS-ENTHALPIES OF BINARY-MIXTURES OF NORMAL-HEPTANE WITH HEXANE ISOMERS [J].

KIMURA, F ;

BENSON, GC ;

HALPIN, CJ .

FLUID PHASE EQUILIBRIA, 1983, 11 (03) :245-250

[5]

MANZINI G, 1974, GAZZ CHIM ITAL, V104, P51

[6] EXCESS-ENTHALPIES, EXCESS VOLUMES, AND EXCESS GIBBS FREE-ENERGIES FOR (NORMAL-HEXANE+NORMAL-DECANE) AT 298.15-K AND 308.15-K [J].

MARSH, KN ;

OTT, JB ;

COSTIGAN, MJ .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1980, 12 (04) :343-348

[7] EXCESS THERMODYNAMIC FUNCTIONS FOR TERNARY-SYSTEMS .1. ACETONE-CHLOROFORM-METHANOL AT 50 DEGREESC [J].

MORRIS, JW ;

MULVEY, PJ ;

ABBOTT, MM ;

VANNESS, HC .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1975, 20 (04) :403-405

[8] DENSITIES, MOLAR VOLUMES, AND CUBIC EXPANSION COEFFICIENTS OF 78 ALIPHATIC ETHERS [J].

OBAMA, M ;

OODERA, Y ;

KOHAMA, N ;

YANASE, T ;

SAITO, Y ;

KUSANO, K .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1985, 30 (01) :1-5

[9] EXCESS-ENTHALPIES, EXCESS VOLUMES, AND EXCESS GIBBS FREE-ENERGIES FOR (N-HEXANE+N-DODECANE) AT 298.15 AND 308.15K [J].

OTT, JB ;

MARSH, KN ;

STOKES, RH .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1981, 13 (04) :371-376

[10] APPLICATION OF A FLOW MICROCALORIMETER TO DETERMINE EXCESS ENTHALPIES OF BINARY-MIXTURES OF NONELECTROLYTES [J].

TANAKA, R ;

DARCY, PJ ;

BENSON, GC .

THERMOCHIMICA ACTA, 1975, 11 (02) :163-175

← 1 2 →