MULTIPLE SPECIES OF LA-AT-THE-COST-OF-C-82 AND Y-AT-THE-COST-OF-C-82 - MASS SPECTROSCOPIC AND SOLUTION EPR STUDIES

被引：91

作者：

HOINKIS, M ^{[1
]}

YANNONI, CS ^{[1
]}

BETHUNE, DS ^{[1
]}

SALEM, JR ^{[1
]}

JOHNSON, RD ^{[1
]}

CROWDER, MS ^{[1
]}

DEVRIES, MS ^{[1
]}

机构：

[1] IBM ADSTAR,SAN JOSE,CA 95193

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 198卷 / 05期

关键词：

D O I：

10.1016/0009-2614(92)80028-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two dominant electron paramagnetic resonance (EPR) hyperfine patterns for both La and Y fullerenes have been identified and linked to the mass spectroscopic (MS) peaks of La@C82 and Y@C82, respectively, as also observed by Suzuki et al. Additionally, lower intensity La@C(n) EPR multiplets are identified which have not, as yet, been correlated with specific MS peaks. The intensity ratios of the two dominant EPR multiplets depend on various parameters such as solvent and temperature, suggesting the species possess different chemical properties.

引用

页码：461 / 465

页数：5

共 13 条

[1] C60LA - A DEFLATED SOCCER BALL
COX, DM
TREVOR, DJ
REICHMANN, KC
KALDOR, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (09) : 2457 - 2458
[2] LANTHANUM COMPLEXES OF SPHEROIDAL CARBON SHELLS
HEATH, JR
OBRIEN, SC
ZHANG, Q
LIU, Y
CURL, RF
KROTO, HW
TITTEL, FK
SMALLEY, RE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (25) : 7779 - 7780
[3] ELECTRON-PARAMAGNETIC RESONANCE STUDIES OF LANTHANUM-CONTAINING C82
JOHNSON, RD
DEVRIES, MS
SALEM, J
BETHUNE, DS
YANNONI, CS
[J]. NATURE, 1992, 355 (6357) : 239 - 240
[4] NMR CHARACTERIZATION OF ISOMERS OF C-78, C-82 AND C-84 FULLERENES
KIKUCHI, K
NAKAHARA, N
WAKABAYASHI, T
SUZUKI, S
SHIROMARU, H
MIYAKE, Y
SAITO, K
IKEMOTO, I
KAINOSHO, M
ACHIBA, Y
[J]. NATURE, 1992, 357 (6374) : 142 - 145
[5] C-60 - BUCKMINSTERFULLERENE
KROTO, HW
HEATH, JR
OBRIEN, SC
CURL, RF
SMALLEY, RE
[J]. NATURE, 1985, 318 (6042) : 162 - 163
[6] LI JY, 1992, J PHYS CHEM-US, V96, P8634
[7] STRUCTURAL PROPOSALS FOR ENDOHEDRAL METAL FULLERENE COMPLEXES
MANOLOPOULOS, DE
FOWLER, PW
[J]. CHEMICAL PHYSICS LETTERS, 1991, 187 (1-2) : 1 - 7
[8] ROSS MM, PREPRINT
[9] ENCAPSULATION OF A SCANDIUM TRIMER IN C82
SHINOHARA, H
SATO, H
OHKOHCHI, M
ANDO, Y
KODAMA, T
SHIDA, T
KATO, T
SAITO, Y
[J]. NATURE, 1992, 357 (6373) : 52 - 54
[10] MASS SPECTROSCOPIC AND ESR CHARACTERIZATION OF SOLUBLE YTTRIUM-CONTAINING METALLOFULLERENES YC82 AND Y2C82
SHINOHARA, H
SATO, H
SAITO, Y
OHKOHCHI, M
ANDO, Y
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (09) : 3571 - 3573

← 1 2 →