INTRA-MOLECULAR DYNAMICS OF 3C-2E BONDED ARYL GROUPS IN POLYNUCLEAR ARYL-COPPER, ARYL-SILVER AND ARYL-GOLD DERIVATIVES

被引：12

作者：

VANKOTEN, G ^{[1
]}

NOLTES, JG ^{[1
]}

机构：

[1] TNO,INST ORGAN CHEM,NL-3502 JA UTRECHT,NETHERLANDS

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 171卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)81550-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dynamic 1H and 13C NMR studies reveal that the prochiral methylene group in 2-(Me2NCH2)C6H4-metal compounds R4M2Li2 (M = Cu, Ag or Au) is an excellent probe for the monitoring of the configuration at C(1) in each of the 2-(Me2NCH2)C6H4MLi units. In this way the rotation of 3c2e bonded aryl groups around the C(1)⋯C(4) axis has been unambiguously establish for the first time. Chiral labelling of the 3c2e bonded group provides information concerning the stereochemistry of the R4M2Li2 cluster. © 1979.

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页码：C39 / C43

页数：5

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