HYDROGEN-BOND ENERGY OF CH3CN-HCL BY FTIR PHOTOMETRY

被引：14

作者：

BALLARD, L ^{[1
]}

HENDERSON, G ^{[1
]}

机构：

[1] EASTERN ILLINOIS UNIV,DEPT CHEM,CHARLESTON,IL 61920

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 02期

关键词：

D O I：

10.1021/j100155a030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The temperature dependence of an IR absorption band of CH3CN-HCI is characterized by FTIR photometry. The heat of dimer formation at 41-degrees-C obtained from this data, DELTA-H(D) = -21.8 +/- 1.7 kJ/mol. is used to calculate the equilibrium hydrogen bond dissociation energy, D(c) = 21.8 +/- 1.7 kJ/mol. These results are compared with recent ab initio theoretical calculations and empirical estimates based on centrifugal distortion parameters.

引用

页码：660 / 663

页数：4

共 14 条

[1] NEW METHOD FOR OBSERVING THE ROTATIONAL SPECTRA OF WEAK MOLECULAR-COMPLEXES - KRHCL
BALLE, TJ
CAMPBELL, EJ
KEENAN, MR
FLYGARE, WH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (02) : 922 - 932
[2] A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS
BENESI, HA
HILDEBRAND, JH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (08) : 2703 - 2707
[3] HYDROGEN-BONDING BETWEEN NITRILES AND HYDROGEN HALIDES AND THE TOPOLOGICAL PROPERTIES OF MOLECULAR CHARGE-DISTRIBUTIONS
BOYD, RJ
CHOI, SC
[J]. CHEMICAL PHYSICS LETTERS, 1986, 129 (01) : 62 - 65
[4] CLAGUE A, 1967, SPECTROCHIM ACTA A, V25, P593
[5] DETERMINATION OF MOLECULAR STRUCTURES FROM GROUND STATE ROTATIONAL CONSTANTS
COSTAIN, CC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1958, 29 (04) : 864 - 874
[6] HYDROGEN-BONDING IN HCN...HF, HCN...HCL, CH3CH...HF AND CH3CH...HCL - AN ABINITIO SCF-MO STUDY
HINCHLIFFE, A
[J]. ADVANCES IN MOLECULAR RELAXATION AND INTERACTION PROCESSES, 1981, 19 (04): : 227 - 237
[7] ROTATIONAL SPECTRUM OF THE HYDROGEN-BONDED DIMER CH3CN...HCL
LEGON, AC
MILLEN, DJ
NORTH, HM
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (20) : 5210 - 5213
[8] HYDROGEN-BONDING IN THE GAS-PHASE - INFRARED SPECTROSCOPIC INVESTIGATION OF HYDROGEN-FLUORIDE ALCOHOL-HETERODIMERS
LEGON, AC
MILLEN, DJ
SCHREMS, O
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1979, 75 : 592 - 601
[9] Pimentel G.C., 1960, HYDROGEN BOND
[10] INFRARED MATRIX-ISOLATION STUDY OF THE MOLECULAR-COMPLEXES BETWEEN ACETONITRILE AND HYDROGEN HALIDES - EVIDENCE FOR REACTIVITY DIFFERENCES WITHIN THE HALIDE SERIES
SCHRIVER, L
SCHRIVER, A
PERCHARD, JP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1985, 81 (SEP): : 1407 - 1425

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