DYNAMICAL SUPERHYPERFINE INTERACTION OF ATOMIC-HYDROGEN IN KC1 AND RBC1

被引：11

作者：

HOENTZSCH, C

SPAETH, JM

机构：

[1] Fachbereich Naturwissenschaften I, Experimentalphysik, Gesamthochschule Paderborn

来源：

PHYSICA STATUS SOLIDI B-BASIC RESEARCH | 1979年 / 94卷 / 02期

关键词：

D O I：

10.1002/pssb.2220940220

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

With ENDOR the shf and quadrupole interactions of the nearest Cl neighbours of atomic deuterium on cation sites in KCl and RbCl and of first‐ and second‐shell neighbours of interstitial deuterium in RbCl are measured. Comparison with previous data of atomic hydrogen shows a distinct isotope effect indicating a considerable influence of the zero‐point vibration on the shf interactions. Using an orthogonalization model including a Cl3pσ covalency, the vibrational potential is determined from the isotope effect. It is shown that this theoretical model cannot explain the measured spin density at the nearest Cl neighbours. Copyright © 1979 WILEY‐VCH Verlag GmbH & Co. KGaA

引用

页码：497 / 503

页数：7

共 15 条

[1]

ADRIAN FJ, COMMUNICATION

[2] PARAMAGNETIC RESONANCE INVESTIGATION OF IRRADIATED KCL CRYSTALS CONTAINING U-CENTERS [J].

DELBECQ, CJ ;

SMALLER, B ;

YUSTER, PH .

PHYSICAL REVIEW, 1956, 104 (03) :599-604

[3]

HARKER AB, COMMUNICATION

[4]

HEDER G, UNPUBLISHED

[5] ESR STUDY OF INTERSTITIAL ATOMIC-HYDROGEN IN ALKALI FLUORIDES [J].

HOENTZSCH, C ;

SPAETH, JM .

SOLID STATE COMMUNICATIONS, 1979, 29 (08) :577-581

[6] LOCALIZED VIBRATIONS OF SUBSTITUTIONAL ATOMIC-HYDROGEN IN KCL AND RBCL STUDIED BY ENDOR [J].

HOENTZSCH, C ;

SPAETH, JM .

PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1978, 88 (02) :581-589

[7]

KUCH W, 1977, THESIS STUTTGART

[8]

PICK H, 1969, OPTICAL PROPERTIES S, P655

[9]

SCHWAN L, 1975, THESIS STUTTGART

[10]

Spaeth J. M., 1970, Physica Status Solidi, V42, P739, DOI 10.1002/pssb.19700420229

← 1 2 →