PHYSICAL-PROPERTIES OF POLYPYRROLE FILMS CONTAINING SULFONATED METALLOPHTHALOCYANINE ANIONS

被引：48

作者：

SAUNDERS, BR ^{[1
]}

MURRAY, KS ^{[1
]}

FLEMING, RJ ^{[1
]}

机构：

[1] MONASH UNIV,DEPT PHYS,CLAYTON,VIC 3168,AUSTRALIA

来源：

SYNTHETIC METALS | 1992年 / 47卷 / 02期

关键词：

D O I：

10.1016/0379-6779(92)90384-U

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Thin films of polypyrrole (PPy) containing tetrasulfonated metallophthalocyanine anions (MTsPc4-, M = Cu, Ni and Co) were prepared electrochemically from aqueous solution in a single-compartment cell. The films were deposited on a platinum anode and had thicknesses in the range 20-100-mu-m. Their room temperature electrical conductivities were of the order 1-10 S cm-1 and were compatible with a variable range hopping model of interchain charge transport between 77 and 300 K. The conductivities fell by approximately 50% when the films were exposed to laboratory air for one week; this reduction appears to be due to irreversible oxygen attack. ESR measurements suggested intercalation of the MTsPc anions between the PPy chains, while X-ray diffraction data indicated a level of structural order comparable with that of PPy-para-toluenesulfonate (PPyPTS).

引用

页码：167 / 178

页数：12

共 44 条

[1] FORMATION OF A 1-1 OXYGEN ADDUCT WITH COBALT(II)-TETRASULPHOPHTHALOCYANINE COMPLEX [J].