PHOTOCATALYTIC REDUCTION OF COORDINATED DINITROGEN TO AMMONIA - MONONUCLEAR VERSUS DINUCLEAR ETHYLENEDIAMINETETRAACETATO RUTHENIUM COMPLEXES

被引：9

作者：

RAO, NN

机构：

[1] Photocatalysis Group, Central Salt and Marine Chemicals Research Institute, Bhavnagar

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 93卷 / 01期

关键词：

DINUCLEAR COMPLEXES; MONONUCLEAR COMPLEXES; NITROGEN; PHOTOCATALYSIS; REDUCTION; RUTHENIUM;

D O I：

10.1016/0304-5102(94)00097-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experiments were conducted aiming for the reduction of coordinated nitrogen in mononuclear end-on dinitrogen complex, [Ru(Hedta) N-2](-) and dinuclear bridged complex, [Ru(Hedta)]N-2(2)2- using the conduction band electrons of illuminated Pt/CdS (lambda(ex) = 505 nm). It has been found that the dinitrogen in mononuclear end-on complex is more easily reduced to ammonia.

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页码：23 / 27

页数：5

相关论文

共 27 条

[21] NITROGEN PHOTO-REDUCTION ON DESERT SANDS UNDER STERILE CONDITIONS [J].

SCHRAUZER, GN ;

STRAMPACH, N ;

HUI, LN ;

PALMER, MR ;

SALEHI, J .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA-PHYSICAL SCIENCES, 1983, 80 (12) :3873-3876

[22] PHOTOLYSIS OF WATER AND PHOTOREDUCTION OF NITROGEN ON TITANIUM-DIOXIDE [J].

SCHRAUZER, GN ;

GUTH, TD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (22) :7189-7193

[23]

SCHRAUZER GN, 1985, HOMOGENEOUS HETEROGE, P509

[24] DINITROGEN PHOTOREDUCTION TO AMMONIA OVER TITANIUM-DIOXIDE POWDERS DOPED WITH FERRIC IONS [J].

SORIA, J ;

CONESA, JC ;

AUGUGLIARO, V ;

PALMISANO, L ;

SCHIAVELLO, M ;

SCLAFANI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (01) :274-282

[25] PHOTOCATALYTIC REDUCTION OF NITROGEN TO AMMONIA WITH COPRECIPITATED FE(III) AND TI(IV) HYDROUS OXIDES [J].

TENNAKONE, K ;

FERNANDO, CAN ;

WICKRAMANAYAKE, S ;

DAMAYANTHI, MWP ;

SILVA, LHK ;

WIJERATNE, W ;

ILLEPERUMA, OA ;

PUNCHIHEWA, S .

SOLAR ENERGY MATERIALS, 1988, 17 (01) :47-53

[26] PHOTOCATALYTIC NITROGEN REDUCTION USING VISIBLE-LIGHT [J].

TENNAKONE, K ;

WICKRAMANAYAKE, S ;

FERNANDO, CAN ;

ILEPERUMA, OA ;

PUNCHIHEWA, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (14) :1078-1080

[27] A SPECTROPHOTOMETRIC METHOD FOR THE DETERMINATION OF HYDRAZINE [J].

WATT, GW ;

CHRISP, JD .

ANALYTICAL CHEMISTRY, 1952, 24 (12) :2006-2008