REACTION OF BROMINE(I) FLUOROSULFATE WITH SOME COVALENT CHLORIDES

被引：36

作者：

DESMARTEAU, DD

机构：

[1] Department of Chemistry, University of Washington, Seattle

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 03期

关键词：

D O I：

10.1021/ic50061a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bromine(I) fluorosulfate has been shown to react with a variety of nonmetal chlorides according to the general equation MCIx + YBrOSO2F = MCx-y(OSC2F)y + YBrCl. New compounds obtained in this manner were [C(0)OSO2F]2, C(O)-C1C(O)OSO2F, CFCl2OSO2F, CFCl(OSO2F)2, CCl(OSO2F)3, C(OSO2F)4, SP(0SO2F)2, POCl2OSO2F, and SiCl2(OSO2F)2. Some evidence was also found for the compounds CCl3OSO2F, CCl2(OSCO2F)2, SOClOSO2F, and POCl(OSO2F)2. © 1968, American Chemical Society. All rights reserved.

引用

页码：434 / +

页数：1

共 21 条

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