SYNTHESIS OF ALKYNES FROM ENOL ESTERS

被引：13

作者：

CRAIG, JC

BERGENTH.MD

FLEMING, I

HARLEYMA.J

机构：

[1] Department of Pharmaceutical Chemistry, University of California School of Pharmacy, San Francisco, California

[2] University Chemical Laboratory, University of Cambridge, Cambridge, Lensfield Road

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1969年 / 8卷 / 06期

关键词：

Alkynes; Enol esters;

D O I：

10.1002/anie.196904291

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Eliminations leading from enol sulfonates, enol phosphates, and enol phosphonium salts to alkynes are reviewed. Olefin eliminations are usually the rate‐determining step in the formation of the triple bond. Enol esters may also play a role in the biosynthesis of alkynes. Copyright © 1969 by Verlag Chemie, GmbH, Germany

引用

页码：429 / &

共 75 条

[1] ANKAMINAMI G, 1962, B CHEM SOC JAPAN, V35, P1629
[2] ARENS JF, 1960, ADVANCES ORGANIC CHE, V2, P121
[3] ACETYLEN-DERIVATE DURCH FRAGMENTIERUNG
BODENDORF, K
KLOSS, P
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1963, 75 (02) : 139 - &
[4] Bodendorf K, 1963, ANGEW CHEM INT EDIT, V2, P98
[5] BOHLMANN F, 1967, FORT CHEM ORG NAT, V25, P1
[6] STRUCTURE AND REACTIVITY OF THE ACETYLENE LINKAGE
BOHLMANN, F
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1957, 69 (03) : 82 - 86
[7] BOHLMANN F, 1957, CHEM ORG NATURSTOFFE, V14, P1
[8] ENOL ELIMINATION REACTIONS .3. SCOPE AND LIMITATIONS OF ELIMINATIONS INVOLVING ENOL SULPHONATES
BROWN, EJD
HARTLEYM.J
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1966, (16): : 1390 - &
[9] Bu'Lock J. D., 1964, PROG ORG CHEM, V6, P86
[10] BIOSYNTHESIS OF POLYACETYLENES .3. POLYACETYLENES AND TRITERPENES IN POLYPORUS ANTHRACOPHILUS
BULOCK, JD
ALLPORT, DC
TURNER, WB
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1961, (APR): : 1654 - &

← 1 2 3 4 5 6 7 8 →