FLASH PHOTOLYSIS-RESONANCE FLUORESCENCE KINETICS STUDY OF THE REACTION OH+NO2+M-]HNO3+M

被引：96

作者：

WINE, PH

KREUTTER, NM

RAVISHANKARA, AR

机构：

[1] Molecular Sciences Group, Engineering Experiment Station, Georgia Institute of Technology, Atlanta

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 25期

关键词：

D O I：

10.1021/j100488a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The flash photolysis-resonance fluorescence technique has been employed to study the kinetics of the combination reaction OH + NO2 + M → HNO3 + M. A total of 57 bimolecular rate constants are reported for varying conditions of temperature (247-352 K), pressure (14-700 torr), and diluent gas identity (He, Ar, N2, SF6). These new rate data are compared with previous measurements, and their significance to atmospheric chemistry and unimolecular rate theory is discussed. © 1979 American Chemical Society.

引用

页码：3191 / 3195

页数：5

共 26 条

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