KINETICS OF THE REACTION OF NH2 WITH NO2

被引：42

作者：

KURASAWA, H

LESCLAUX, R

机构：

[1] Laboratoire de Chimie-Physique A, Université de Bordeaux I

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80350-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absolute rate constant of the reaction of NH2 with NO2 has been measured using a flash-photolysis laser resonance-fluorescence technique. The value obtained at room temperature is k1 = 2.3 (± 0.2) × 10-11 cm3 molecule -1 s-1. A negative temperature coefficient has been found between 298 and 505 K for this reaction, k1 = 3.8 × 10-8 × T-1.30 cm3 molecule-1 s-1. It is thought that this is the major reaction of NH2 in the troposphere. © 1979.

引用

页码：602 / 607

页数：6

共 15 条

[1] REACTION BETWEEN AMMONIA AND NITROGEN-DIOXIDE [J].