HYDROXYLATED JASMONIC ACID AND RELATED-COMPOUNDS FROM BOTRYODIPLODIA-THEOBROMAE

被引：39

作者：

MIERSCH, O

SCHNEIDER, G

SEMBDNER, G

机构：

来源：

PHYTOCHEMISTRY | 1991年 / 30卷 / 12期

关键词：

BOTRYODIPLODIA-THEOBROMAE; SPHAEROPSIDACEAE; (11R)-HYDROXYJASMONIC ACID; (11S)-(-)-HYDROXYJASMONIC ACID; (-)-12-HYDROXYJASMONIC ACID; (-)-8-ZETA-HYDROXYJASMONIC ACID; (-)-3-OXO-2-(1-ZETA-HYDROXY-2Z-PENTENYL)CYCLOPENT-1-YL-BUTYRIC ACID; (-)-3-OXO-2-(4-ZETA-HYDROXY-2Z-PENTENYL)CYCLOPENT-1-YL-BUTYRIC ACID;

D O I：

10.1016/0031-9422(91)83464-V

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

From the culture filtrate of the fungus Botryodiplodia theobromae five hydroxylated cyclopentane fatty acids of the jasmonic acid type were isolated and identified as (11S)-(-)-hydroxyjasmonic acid; (11R)-(-)-hydroxyjasmonic acid; (-)-12-hydroxyjasmonic acid; (-)-8-xi-hydroxyjasmonic acid; (-)-3-oxo-2-(1-xi-hydroxy-2Z-pentenyl)cyclopent-1-yl-butyric acid, and (-)-3-oxo-2(4-xi-hydroxy-2Z-pentenyl)cyclopent-1-yl-butyric acid. In addition, the corresponding hydroxylated iso-jasmonic acid analogues were found as minor constituents. During silica gel chromatography 11,12-didehydrojasmonic acid, 11-xi-acetoxyjasmonic acid, 3-oxo-2-(4-xi-acetoxy-2Z-pentenyl)cyclopent-1-yl-butyric acid and 3-oxo-2-(2Z,4-pentadienyl)cyclopent-1-yl-butyric acid were formed as artefacts.

引用

页码：4049 / 4051

页数：3

共 17 条

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