MACROCYCLIC (C22H22N4) COMPLEXES OF GERMANIUM(II), TIN(II), GALLIUM(III), AND INDIUM(III) - MAIN GROUP FUNCTIONALITIES IN UNUSUAL ENVIRONMENTS

被引：45

作者：

ATWOOD, DA

ATWOOD, VO

COWLEY, AH

ATWOOD, JL

ROMAN, E

机构：

[1] UNIV TEXAS, DEPT CHEM & BIOCHEM, AUSTIN, TX 78712 USA

[2] UNIV ALABAMA, DEPT CHEM, TUSCALOOSA, AL 35486 USA

[3] CTR INVEST MINERAS & MET, SANTIAGO, CHILE

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 19期

关键词：

D O I：

10.1021/ic00045a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Li2(tmtaa) (tmtaa = dibenzotetramethyl-tetraaza[14]annulene) tetraaza[14]annulene) with GeCl2.dioxane, SnCl2, GaCl3, and InCl3 affords the complexes Ge(tmtaa) (1), Sn(tmtaa) (3), Ga(tmtaa)Cl (5), and In(tmtaa)-Cl (6), respectively. The structures of 1, 3, and 5 have been determined by X-ray analysis. Compounds 1 and 3 react with (THF)Cr(CO)5 to produce the bimetallic derivatives (tmtaa)MCr(CO)5 (2, M = Ge; 4, M = Sn). The Ga-Cl bond of 5 is very unreactive; however, 6 will undergo slow reaction with MeLi to afford In(tmtaa)Me (7).

引用

页码：3871 / 3872

页数：2

共 5 条

[1] OLIGOMERIC GALLIUM AMIDE/HYDRIDE COMPLEXES, [H2GA2((NPRICH2)2)2] AND [H5GA3((NMECH2)2)2], VIA HYDROMETALLATION AND METALATION [J].