TIN-OXYGEN-PHOSPHORUS COMPOUNDS

被引:42
作者
RIDENOUR, RE
FLAGG, EE
机构
[1] Chemicals Laboratory, The Dow Chemical Company, Midland
关键词
D O I
10.1016/S0022-328X(00)89764-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Four types of tin-oxygen-phosphorus compounds are described and characterized. All of the compounds are oligomeric and incorporate either phosphinato or phosphonato bridging. Physical data are consistent with 5-coordinate tin for triorganotin diorganophosphinates, (I); both 4- and 5-coordinate tin for bis(triorganotin) organophosphonates, (II); 5-coordinate tin for poly(diorganotin organophosphonates), (III); and 6-coordinate tin for diorganotin bis(diorganophosphinates), (IV). Structures are proposed on the basis of molecularity, infrared, NMR, and Mössbauer data. © 1969.
引用
收藏
页码:393 / &
相关论文
共 26 条