MOLECULAR PARAMETERS AND BOND STRUCTURE .8. ENVIRONMENTAL EFFECTS ON V(C=N) BOND STRETCHING FREQUENCIES

被引:47
作者
THOMAS, BH
ORVILLET.WJ
机构
[1] Department of Chemistry, Sir John Cass College
[2] Department of Chemistry and Applied Chemistry, University of Sal ford
关键词
D O I
10.1016/0022-2860(69)87003-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The vibrational frequencies associated with the characteristic bands arising from CN bonds have been determined for a number of nitriles in different phases and in various solvents. Some dependence is found on the molecular environment of the CN vibrator. Frequency assignments are given for cyanogen, cyanogen bromide and cis-and trans-1-cya.no-1,3-butadiene. © 1969.
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页码:191 / &
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