BIDENTATE CHELATING AGENT, 8-DIMETHYLARSINOQUINOLINE .2.

被引：6

作者：

BARCLAY, GA

COLLARD, MA

HARRIS, CM

KINGSTON, JV

机构：

[1] School of Chemistry, University of N.S.W., Kensington, NSW

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 11期

关键词：

D O I：

10.1016/0022-1902(69)80337-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mono- and bis-chelates of univalent copper and gold, and bis-chelated complexes of monovalent silver, have been isolated using the bidentate chelating agent 8-dimethylarsinoquinoline (AsN, Fig. 1). Physico-chemical measurements of the mono-chelated copper(I) complexes Cu(AsN)X indicate the presence of both a salt-like species [Cu(AsN)2][CuX2] and a non-conducting form Cu(AsN)X in solution, while similar measurements on the analogous gold(I) compounds, Au(AsN)X, preclude the salt-like structure. The isolation of the apparently five co-ordinate copper (II) complex [Cu(AsN)2(NO3)]NO3 is also reported. © 1969.

引用

页码：3509 / &

共 9 条

[1] BIDENTATE CHELATING AGENT 8-DIMETHYLARSINOQUINOLINE .1. 4-CO-ORDINATE 5-CO-ORDINATE AND 6-CO-ORDINATE COMPLEXES OF DIVALENT PALLADIUM AND PLATINUM [J].