CYCLOADDITION REACTIONS ACROSS THE TI=O BOND OF (TMTAA)TI=O (TMTAA = DIANION OF 7,16-DIHYDRO-6,8,15,17-TETRAMETHYLDIBENZO[B,I][1,4,8,11]TETRAAZACYCLOTETRADECINE)

被引：36

作者：

HOUSMEKERIDES, CE

PILATO, RS

GEOFFROY, GL

RHEINGOLD, AL

机构：

[1] PENN STATE UNIV, DEPT CHEM, UNIVERSITY PK, PA 16802 USA

[2] UNIV DELAWARE, DEPT CHEM, NEWARK, DE 19716 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 08期

关键词：

D O I：

10.1039/c39910000563

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex (tmtaa)Ti = O undergoes [2 + 2] cycloaddition of the Ti = O bond across the C = O bond of ketones and [(C5Me5)Re(CO)2(NO)]+, the S = O bonds of SO2 and SO3, the C = S bond of CS2, and ring opens epoxides and cyclic anhydrides to give metallacycles.

引用

页码：563 / 566

页数：4

共 17 条

[1] SELECTIVE ETHYLENE-OXIDE HYDROLYSIS CATALYZED BY OXO-MOLYBDENUM SPECIES
BRIGGS, JR
HARRISON, AM
ROBSON, JH
[J]. POLYHEDRON, 1986, 5 (1-2) : 281 - 287
[2] ROOM-TEMPERATURE GENERATION OF REACTIVE INTERMEDIATES (CP-STAR)2-ZR=O AND (CP-STAR)2-ZR=S - TRAPPING REACTIONS WITH UNSATURATED ORGANIC-MOLECULES AND DATIVE LIGANDS
CARNEY, MJ
WALSH, PJ
BERGMAN, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (17) : 6426 - 6428
[3] A REACTIVE ORGANOMETALLIC OXO INTERMEDIATE, (CP-STAR)2 ZR=O - GENERATION AND SUBSEQUENT TRAPPING REACTIONS FORMING ALKYNE AND NITRILE ADDITION-PRODUCTS
CARNEY, MJ
WALSH, PJ
HOLLANDER, FJ
BERGMAN, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (23) : 8751 - 8753
[4] MULTIPLE BONDS BETWEEN MAIN GROUP ELEMENTS AND TRANSITION-METALS .55. ALKYNE COORDINATION TO ORGANORHENIUM OXIDES WITH RHENIUM IN HIGH OXIDATION-STATES
FELIXBERGER, JK
KUCHLER, JG
HERDTWECK, E
PACIELLO, RA
HERRMANN, WA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (07): : 946 - 948
[5] NEW MACROCYCLIC COMPLEXES OF TITANIUM(IV) - SYNTHESIS, REACTIVITY, AND X-RAY CRYSTAL-STRUCTURE OF THE TRIGONAL PRISMATIC TI(C22H22N4)CL2, AND SYNTHESIS AND REACTIVITY OF ITS PEROXO, DISULFIDO, AND PYROCATECHOLATO DERIVATIVES
GOEDKEN, VL
LADD, JA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (02) : 142 - 144
[6] ESSAYS ON ORGANOMETALLIC CHEMISTRY .5. RHENIUM CHEMISTRY IN CATALYSIS - PRESENT AND FUTURE
HERRMANN, WA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 382 (1-2) : 1 - 18
[7] HIGH OXIDATION-STATE ORGANOMETALLIC CHEMISTRY, A CHALLENGE - THE EXAMPLE OF RHENIUM
HERRMANN, WA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (10) : 1297 - 1313
[8] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .71. OPEN-CHAIN AND CYCLIC ORGANORHENIUM COMPLEXES OF PI-AROMATIC LIGANDS - OXYGEN-CONTAINING, SULFUR-CONTAINING, AND SELENIUM-CONTAINING DERIVATIVES - STRONG STATIC TRANS INFLUENCE IN THE CRYSTAL AND MOLECULAR-STRUCTURE OF DI-MU-SULFIDO-BIS[OXO(ETA-5-PENTAMETHYL-CYCLOPENTADIENYL)RHENIUM(V)]
HERRMANN, WA
JUNG, KA
HERDTWECK, E
[J]. CHEMISCHE BERICHTE-RECUEIL, 1989, 122 (11): : 2041 - 2048
[9] JORGENSEN KA, 1989, CHEM REV, V89, P431
[10] Meyer Beat, 1977, SULFUR ENERGY ENV

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