THE ENTHALPY OF FORMATION OF THE HSO RADICAL

被引：40

作者：

BALUCANI, N ^{[1
]}

CASAVECCHIA, P ^{[1
]}

STRANGES, D ^{[1
]}

VOLPI, GG ^{[1
]}

机构：

[1] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 211卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(93)87092-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The enthalpy of formation, DELTAH(f,0), 0 of the HSO radical has been determined to be -0.9+/-0.7 kcal/mol from the analysis of high-resolution crossed beam reactive scattering experiments on the reaction O(3P) + H2S-->HSO + H at different collision energies. The results are compared with previous experimental and theoretical estimates.

引用

页码：469 / 472

页数：4

共 33 条

[1]

ATKINSON R, 1992, J PHYS CHEM REF DATA, V21, P1566

[2] THE EFFECT OF REAGENT ELECTRONIC-ENERGY ON THE DYNAMICS OF CHEMICAL-REACTIONS - A HIGH-RESOLUTION CROSSED BEAM STUDY OF O(P-3, 1D) + H2S [J].

BALUCANI, N ;

BENEVENTI, L ;

CASAVECCHIA, P ;

STRANGES, D ;

VOLPI, GG .

JOURNAL OF CHEMICAL PHYSICS, 1991, 94 (12) :8611-8614

[3] DYNAMICS OF THE REACTION O(1D)+HCL-]CLO+H FROM CROSSED-BEAM EXPERIMENTS [J].

BALUCANI, N ;

BENEVENTI, L ;

CASAVECCHIA, P ;

VOLPI, GG .

CHEMICAL PHYSICS LETTERS, 1991, 180 (1-2) :34-40

[4]

BALUCANI N, IN PRESS

[5] HIGH-RESOLUTION TOTAL DIFFERENTIAL CROSS-SECTIONS FOR SCATTERING OF HELIUM BY O-2, N-2, AND NO [J].

BENEVENTI, L ;

CASAVECCHIA, P ;

VOLPI, GG .

JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (12) :7011-7029

[6]

BENEVENTI L, 1992, 1991 XVII ICPEAC BRI, P527

[7] THERMOCHEMISTRY AND KINETICS OF SULFUR-CONTAINING MOLECULES AND RADICALS [J].

BENSON, SW .

CHEMICAL REVIEWS, 1978, 78 (01) :23-35

[8] REACTIONS OF HS WITH NO AND NO2 AT 298-K [J].

BLACK, G .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (03) :1103-1107

[9]

BUENKER RJ, 1980, ISRAEL J CHEM, V19, P309

[10]

CASAVECCHIA P, 1991, FARADAY DISCUSS, V91, P147

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