SYNTHESIS AND CHARACTERIZATION OF VANADIUM(III) AND OXOVANADIUM(IV/V) SPECIES WITH DEPROTONATED AMIDE LIGANDS

被引：14

作者：

KABANOS, TA ^{[1
]}

KERAMIDAS, AD ^{[1
]}

PAPAIOANNOU, AB ^{[1
]}

TERZIS, A ^{[1
]}

机构：

[1] NRPCS DEMOKRITOS,INST MAT SCI,GR-15310 AGIA PARASKEVI A,GREECE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 07期

关键词：

D O I：

10.1039/c39930000643

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the amide ligand N-[2-(2-pyridylmethyleneamino)phenyl]pyridine-2-carboxamide (Hcapca) with VCl3 affords the compound trans-[VCl2(capca)] 1, the first example of a vanadium(III) complex containing a vanadium-deprotonated amide nitrogen bond, while reaction of bis(pentane-2,4-dionato)oxovanadium(IV) with the related ligands 1,2-bis(2-hydroxybenzamido)benzene (H-4hybeb) and 1-(2-hydroxybenzamido)-2-(2-pyridinecarboxamido)benzene (H-3hypyb) yields the complexes Na2[VIVO(hybeb)] 2 and Na[VIVO(hypyb)] 3 respectively; the X-ray crystal structures of 1 and 3 are reported.

引用

页码：643 / 645

页数：3

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