STEPS AND KINKS ON =211] IRON SURFACES AND THE KINETICS OF THE IRON ELECTRODE

被引：48

作者：

ALLGAIER, W

HEUSLER, KE

机构：

[1] SONDERFORSCH BEREICH 126,GOTTINGEN,FED REP GER

[2] TECH UNIV CLAUSTHAL,KORROS ABT,D-3392 CLAUSTHAL,FED REP GER

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1979年 / 9卷 / 02期

关键词：

D O I：

10.1007/BF00616085

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The quantitative analysis of the morphology of dislocation-free {211} iron surfaces during electrochemical dissolution and measurements of distances and directions of monatomic steps provide information about the rates and potential dependences of three different elementary processes involving iron atoms bound to the lattice in three geometrically and energetically different states. The interaction of the three elementary processes explains the well-known anomalies of the kinetics of the iron electrode. A statistical analysis of the step distances is given. © 1979 Chapman and Hall Ltd.

引用

页码：155 / 160

页数：6