STUDY OF THE ROTATIONAL CORRELATION-FUNCTION FOR CYCLOHEXANE BY RAMAN-SCATTERING

被引:16
作者
BANSAL, ML
ROY, AP
机构
[1] Solid State Physics Section, Bhabha Atomic Research Centre, Bombay
关键词
D O I
10.1080/00268977900102531
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The rotational correlation function of cyclohexane has been obtained by Raman spectroscopy in the liquid and plastic crystal phase. The characteristic relaxation time for reorientation of the molecular symmetry axis rises from 0-6 ps at 345 K to 2-5 ps at 195 K. Comparison with the J and M extended diffusion model indicates closer agreement with the latter. © 1979 Taylor and Francis Ltd.
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页码:1419 / 1426
页数:8
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